Preheat the oven: Preheat the oven to 340°F (170°C). Line a 9 × 5-inch loaf pan with parchment paper, leaving some overhang on the sides.
Prepare the zucchini: Wash the zucchini, trim the ends, and grate it using the large holes of a box grater. Do not peel or squeeze out the liquid.
Mix the wet ingredients: Place the grated zucchini in a large bowl. Add the eggs, vegetable oil, sugar, and vanilla extract. Whisk until evenly combined.
Combine the dry ingredients: In a separate bowl, whisk together the flour, cocoa powder, baking soda, baking powder, salt, and instant coffee granules. Break up any cocoa lumps.
Make the batter: Add the wet zucchini mixture to the dry ingredients. Gently fold with a spatula just until no dry flour remains. Do not overmix.
Add the chocolate: Fold in the dark chocolate chips or chopped chocolate until evenly distributed.
Fill the pan: Transfer the batter to the prepared loaf pan and smooth the top. Sprinkle with additional chocolate chips, if desired.
Bake: Loosely cover the pan with aluminum foil and bake for 40-50 minutes. Remove the foil approximately 15 minutes before the end of baking so the top can set
Check for doneness: Insert a toothpick into the center. It should come out with a few moist crumbs but no wet batter. Keep in mind that melted chocolate may appear on the toothpick.
Cool: Let the bread cool in the pan for about 10-15 minutes, then lift it out using the parchment paper. Serve slightly warm or allow it to cool completely before slicing.